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This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.

Many papers have been written for SAE on electrochemical metallizing, a modern term for “selective” or “brush” plating. These papers have dealt primarily with the aerospace industry, including the use of non-embrittling cadmium LHE® coatings for corrosion protection on aircraft. Shadowed by 30 years of successes in the aerospace industry, electrochemical metallizing corrosion protection in the automotive industry is often overlooked. Specifically, the use of selectively applied zinc coatings for corrosion protection on wheel hubs during manufacture has proven integral at several European automotive manufacturers. In the past, environmental conditions have corroded both the hubs and wheels of automobiles. Quite often the corrosion is in the microscopic gap between the hub and the wheel, which over time causes the wheel to seize and prevents removal. This has been frustrating to both stranded motorists and shop mechanics.

Vacuum brazing technology is currently capable of producing aluminum automotive heat exchangers such as radiators and heater cores. The possible use of 7072 claddings on the surfaces exposed to the coolant to provide additional corrosion protection is of considerable interest. This paper describes the effect of typical vacuum brazing cycles on the distribution of zinc in 7072 clad vacuum brazing sheet. For heavier gauges (.05″), there is sufficient retained zinc in the post-braze composite. For lighter gauges (.02″ or less), nominal composition 7072 does not provide adequate retained zinc; however, if the initial zinc concentration is increased to 3% there is sufficient retained zinc so that the cladding is significantly more anodic than the core.

AS PART of its continuing research to improve the die casting process, International Lead Zinc Research Organization, Inc. has prepared a computer program, “Computer-Aided Design for Zinc Die Casting Dies,” which will enable a die caster to design the metal flow system for a die within a matter of minutes—simply and more accurately than ever possible, previously. It is helping convert what has been an art into a science.

The role of zinc die castings in the materials marketplace has changed significantly in the last generation. In response to a shift in the available market, the industry has made major advances intended to improve competitiveness in both traditional and non-traditional areas. Better efficiency and performance have been achieved by the application of new methods and technologies. The ZA alloys, introduced to die casting during the last decade, have markedly expanded the capabilities of both zinc and the die casting process. This paper presents a review of several zinc die castings used in automatic applications.

Zinc die casting products and metal casting processes continue to evolve for the benefit of end users. Through cooperative global research programs continuous improvements are still being made to the broad range of excellent mechanical properties, easy castability and the wide choice of finishes available for zinc die castings. Recent advances will be highlighted with case histories specific to automotive applications.

Because of the drastic chilling involved in die casting and the fact that the solid solubilities of both aluminum and copper in zinc change with temperature, these alloys are subject to some aging changes, one of which is a dimensional change. Both of the alloys undergo a slight shrinkage after casting, which at room temperature is about two-thirds complete in five weeks. It is possible to accelerate this shrinkage by a stabilizing anneal, after which no further changes occur. The recommended stabilizing anneal is 3 to 6 h at 100 °C (212 °F), or 5 to 10 h at 85 °C (185 °F), or 10 to 20 h at 70 °C (158 °F). The time in each case is measured from the time at which the castings reach the annealing temperature. The parts may be air cooled after annealing. Such a treatment will cause a shrinkage (0.0004 in per in) of about two-thirds of the total, and the remaining shrinkage will occur at room temperature during the subsequent few weeks.

Provision of a layer of zinc on aluminium to provide the fillets for soldering is well established but this usually necessitates a thick layer of zinc (>30μm) and soldering at temperatures below 450°C. New technology has been developed to enable sound joints to be made on aluminium heat exchangers using a much thinner layer of zinc (4 to 8 μm typically) on the aluminium component to provide the joint. By the correct combination of flux and zinc coating thickness, joints have been obtained over a wide range of heating conditions. Preferred temperature cycles are similar to those used by the industry today for brazing of Aluminium:Silicon braze-clad aluminium components which should facilitate tranfer by industry to the new technology.

Traditional and new zinc-based casting alloys for functional and decorative applications are reviewed. Their compositions and standard alloy specifications are described, and recommendations for casting process selection and prototyping of applications are offered. The information presented shows the versatility achievable with zinc alloys. It is aimed at helping part designers make the most effective use of zinc for their component requirements.

High damping capacity materials are useful in attenuating vibrations in mechanical structures such as functional automotive bracketry. The intrinsic damping properties of zinc alloys have only recently been systematically measured. Low and high frequency damping experiments have been conducted on die cast zinc alloys. and damping capacity has been measured as a function of temperature at high frequencies. The alloys show excellent damping properties over the range from 5 Hertz to a few hundred Hertz. for service applications from 40-80°C (104-176°F).

SIMILAR SPECIFICATIONS—UNS Z33521, former SAE 903, ingot is similar to ASTM B 240-79, Alloy AG40A; and UNS Z33520, former SAE 903, die casting is similar to ASTM B 86-76, Alloy AG40A. UNS Z35530, former SAE 925, ingot is similar to ASTM B 240-79, Alloy AC41A; and UNS Z35531, former SAE 925, die casting is similar to ASTM B 86-82a, Alloy AC41A.

The ZA series of zinc alloys produce high strength die castings with the same cast-to size capability as the well proven SAE 903 alloy. The enhanced properties have been utilised in the two engine components described in this paper. ZA 27 has been used for the tooth belt drive camshaft pulley of a motorcycle engine and ZA8 has been used for the temperature resistant housing of a car ignition distributor.

This specification covers a zinc alloy in the form of die castings.

This specification covers a zinc alloy in the form of die castings.

This specification covers a zinc alloy in the form of die castings.

Internal combustion engines development with increased complexity due to CO2 reduction and emissions regulation, while reducing costs and duration of development projects, makes numerical simulation essential. 1D engine simulation software response for the gas exchange process is sufficiently accurate and quick. However, combustion simulation by Wiebe function is poorly predictive. The objective of this paper is to compare different approaches for 0D Spark Ignition (SI) modeling. Versions of Eddy Burn Up, Fractal and Flame Surface Density (FSD) models have been coded into GT-POWER platform, which connects thermodynamics, gas exchange and combustion sub-models. An initial flame kernel is imposed and then, the flame front propagates spherically in the combustion chamber. Flame surface is tabulated as a function of piston position and flame radius. The modeling of key features of SI combustion such as laminar flame speed and thickness and turbulence was common.

This study aims at a new concept for a fast catalyst light-off in combining a latent heat storage with a catalyst. The arrangement of a latent heat storage device into the exhaust system offers significant benefits for the catalyst light-off. Different arrangements have been examined. The first arrangement, called the sequential arrangement, comprises a latent heat storage device and a subsequent catalyst. This offers a significantly faster heat up of the catalyst compared to the standard arrangement. By that emissions during the cold start phase can be significantly reduced. The setup of the latent heat storage device is designed for a high heat transfer between storage material and the exhaust gas. A second integrated arrangement of a latent heat storage and a catalyst into one common substrate has also been set up and investigated. The main advantage of this arrangement is that the catalyst itself is kept on its operation temperature during the engine off time.

Spacecraft life support equipment is often challenged with two phase flow, where liquid and gas exist together. In the zero gravity environment of an orbiting spacecraft, the behavior of a liquid/gas interface is dominated by forces not usually observed in one “G” due to the overwhelming effects of gravity. The normal perceptions no longer apply. Water does not run down hill and bubbles do not rise to the surface. Surface energy, capillary forces, wetting characteristics and momentum effects predominate. Techniques and equipment have been developed to separate the liquid/gas mixture into its constituent parts with various levels of efficiency and power consumption.